Maybe not better than Kroll, and as Cody said it is hard to compare to Jeselnik's, but I prefer Schumer to Jeselnik Offensive.
The sketches have gotten better since the first episode and the stand up segments are great. Her interviews at the end, I could take or leave. The "man-on-the-street" interviews provide humor as well. Either way, whether or not you think this is as good as Kroll Show or Jeselnik Offensive, Comedy Central has been on fire with their shows.
Nice to see something other than Tosh.0.